Tài liệu Nanochemistry, biotechnology, nanomaterials, and their applications

Springer Proceedings in Physics 214 Olena Fesenko Leonid Yatsenko Editors Nanochemistry, Biotechnology, Nanomaterials, and Their Applications Selected Proceedings of the 5th International Conference Nanotechnology and Nanomaterials (NANO2017), August 23-26, 2017, Chernivtsi, Ukraine Springer Proceedings in Physics Volume 214 The series Springer Proceedings in Physics, founded in 1984, is devoted to timely reports of state-of-the-art developments in physics and related sciences. Typically based on material presented at conferences, workshops and similar scientific meetings, volumes published in this series will constitute a comprehensive up-to-date source of reference on a field or subfield of relevance in contemporary physics. Proposals must include the following: – – – – – name, place and date of the scientific meeting a link to the committees (local organization, international advisors etc.) scientific description of the meeting list of invited/plenary speakers an estimate of the planned proceedings book parameters (number of pages/ articles, requested number of bulk copies, submission deadline). More information about this series at http://www.springer.com/series/361 Olena Fesenko • Leonid Yatsenko Editors Nanochemistry, Biotechnology, Nanomaterials, and Their Applications Selected Proceedings of the 5th International Conference Nanotechnology and Nanomaterials (NANO2017), August 23–26, 2017, Chernivtsi, Ukraine 123 Editors Olena Fesenko National Academy of Sciences of Ukraine Institute of Physics Kyiv, Ukraine Leonid Yatsenko National Academy of Sciences of Ukraine Institute of Physics Kyiv, Ukraine ISSN 0930-8989 ISSN 1867-4941 (electronic) Springer Proceedings in Physics ISBN 978-3-319-92566-0 ISBN 978-3-319-92567-7 (eBook) https://doi.org/10.1007/978-3-319-92567-7 Library of Congress Control Number: 2018948698 © Springer International Publishing AG, part of Springer Nature 2018 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by the registered company Springer International Publishing AG part of Springer Nature. The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland Preface This book highlights the most recent advances in nanoscience from leading researchers in Ukraine, Europe, and beyond. It features contributions from participants of the 5th International research and practice Conference “Nanotechnology and Nanomaterials” (NANO-2017), held in Chernivtsi, Ukraine on August 23–26, 2017. This event was organized jointly by the Institute of Physics of the National Academy of Sciences of Ukraine, Ivan Franko National Chernivtsi National University (Ukraine), University of Tartu (Estonia), University of Turin (Italy), and Pierre and Marie Curie University (France). Internationally recognized experts from a wide range of universities and research institutes shared their knowledge and key results in the areas of nanocomposites and nanomaterials, nanostructured surfaces, microscopy of nano-objects, nanooptics and nanophotonics, nanoplasmonics, nanochemistry, nanobiotechnology, and surface enhanced spectroscopy. Nowadays nanotechnology is becoming the most actively developing and promising field of science. Numerous nanotechnology investigations are already producing practical results that can be applied in various areas of human life from science and technology to medicine and pharmacology. The aim of the present book is to highlight the latest investigations from different areas of nanoscience and to stimulate new interest in this field. Volume II of this two-volume work covers such important topics as nanocomposites, nanochemistry, nanobiotechnology, and enhanced vibrational spectroscopy. This book is divided into two sections—Part I: Nanochemistry and Biotechnology; and Part II: Nanocomposites and Nanomaterials. Sections covering Nanoscale Physics, Nanooptics and Photonics, and Nanostructured Interfaces and Surfaces can be found in Volume I. The papers published in these five sections fall under the broad categories of nanomaterial preparation and characterization, nanobiotechnology, nanodevices and v vi Preface quantum structures, and spectroscopy and nanooptics. We hope that both volumes will be equally useful and interesting for young scientists or PhD students and mature scientists alike. Kyiv, Ukraine Olena Fesenko Leonid Yatsenko Contents Part I Nanochemistry and Biotechnology 1 2 3 4 5 6 Nanostructured Functional Coatings of Iron Family Metals with Refractory Elements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Maryna V. Ved’, Nikolay D. Sakhnenko, Iryna Yu. Yermolenko, and Tatyana A. Nenastina Multifunctional Magnetic Nanocomposites on the Base of Magnetite and Hydroxyapatite for Oncology Applications . . . . . . . . . Ie. V. Pylypchuk, M. V. Abramov, A. L. Petranovska, S. P. Turanksa, T. M. Budnyak, N. V. Kusyak, and P. P. Gorbyk Structural Peculiarities and Properties of Silver-Containing Polymer Nanocomposites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V. Demchenko, S. Riabov, S. Kobylinskyi, L. Goncharenko, and N. Rybalchenko 3 35 49 Effect of Incorporated Inorganic Nanoparticles on Porous Structure and Functional Properties of Strongly and Weakly Acidic Ion Exchangers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ludmila Ponomarova, Yuliya Dzyazko, Yurii Volfkovich, Valentin Sosenkin, and Sergey Scherbakov 63 Peculiarities of the Crystal-Chemical Structure of Spinel Ferrites Cox Fe3-x O4 (0.25 ≤ x ≤1) Obtained Under the Action of a Low-Temperature Contact Nonequilibrium Plasma . . . . . . . . . . . . . . L. A. Frolova, O. A. Pivovarov, O. A. Kushnerov, and N. M. Tolstopalova 79 The Dynamics of Water Molecules Confined in the Interior of DMPC Phospholipid Reverse Micelle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D. Makieła, Przemysław Raczyński, and Zygmunt Gburski 89 vii viii 7 Contents Applications Perspectives of Nanodispersed Chalcogenides of Transition Metals in Photocatalysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Iryna Ivanenko, Tetiana Dontsova, and Yurii Fedenko 99 8 Nanocomposites Based on Thermosetting Polyurethane Matrix and Chemically Modified Multiwalled Carbon Nanotubes . . . . . . . . . . . . 115 L. V. Karabanova, R. L. Whitby, V. A. Bershtein, P. N. Yakushev, A. W. Lloyd, and S. V. Mikhalovsky 9 Polymeric Composite Films with Controlled Release of Natural Antioxidant Enoxil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Roman Kozakevych, Yulia Bolbukh, Lucian Lupascu, Tudor Lupascu, and Valentin Tertykh 10 High-Temperature Electrochemical Synthesis of Nanostructured Coatings of Molybdenum (Tungsten)–Nickel (Cobalt) Alloys and Intermetallic Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Viktor Malyshev, Nataliia Uskova, Dmytro Shakhnin, Tetiana Lukashenko, Viktor Antsibor, and Zafer Ustundag 11 Structure and Electrical/Dielectric Properties of Ion-Conductive Polymer Composites Based on Aliphatic Epoxy Resin and Lithium Perchlorate Salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 Liubov K. Matkovska, Maksym V. Iurzhenko, Yevgen P. Mamunya, Valeriy Demchenko, and Gisele Boiteux 12 Mechanical and Thermal Characteristics of Irradiation Cross-linked Hydrogels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 O. Nadtoka, N. Kutsevol, A. Onanko, and V. Neimash 13 Nanostructural and Nanochemical Processes in Peloid Sediments Aided with Biogeocenosis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215 A. V. Panko, I. G. Kovzun, O. M. Nikipelova, V. A. Prokopenko, O. A. Tsyganovich, and V. O. Oliinyk Part II Nanocomposites and Nanomaterials 14 Directional Synthesis of SnO2 -Based Nanostructures for Use in Gas Sensors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 Svitlana Nahirniak, Tetiana Dontsova, and Ihor Astrelin 15 “Polymer–Oxide” Micro-/Nanocomposites: Background and Promises . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247 S. G. Nedilko 16 Interactions Between Carbon-Based Nanostructures and Biomembranes: Computer Simulations Study . . . . . . . . . . . . . . . . . . . . . 277 Przemysław Raczyński, Mateusz Pabiszczak, and Zygmunt Gburski Contents ix 17 Percolation Threshold of 5-Cyanobiphenyl Mesogene Phases Between Graphene Planes: Computer Simulation Study . . . . . . . . . . . . . . 289 Violetta Raczyńska, Krzysztof Górny, Przemysław Raczyński, and Zbigniew Dendzik 18 The Ultrasonic Treatment as a Promising Method of Nanosized Oxide CeO2 -MoO3 Composites Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 297 V. A. Zazhigalov, O. V. Sachuk, O. A. Diyuk, V. L. Starchevskyy, S. V. Kolotilov, Z. Sawlowicz, S. M. Shcherbakov, and O. I. Zakutevskyy 19 High-Temperature Electrochemical Synthesis of Nanopowders of Tungsten Carbide in Ionic Melts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 311 Viktor Malyshev, Angelina Gab, Dmytro Shakhnin, Tetiana Lukashenko, Oleksandr Ishtvanik, and Marcelle Gaune-Escard 20 Magnetic Memory of Antitumor Magneto-sensitive Nanocomplex . . . 323 V. Orel, A. Shevchenko, O. Rykhalskyi, A. Romanov, A. Burlaka, and S. Lukin 21 Nonlinear Optical Properties of Polymer Nanocomposites with a Random and Periodic Distribution of Silver Nanoparticles . . . . . . . . . 333 T. N. Smirnova, V. I. Rudenko, V. O. Hryn 22 The Nanocomposite Diffusion Coating of Details Prepared of Boriding . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345 Andrew Stetsko 23 Ni Addition Induced Changes in Structural, Magnetic, and Cationic Distribution of Zn0.75−x Nix Mg0.15 Cu0.1 Fe2 O4 Nano-ferrite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 357 Manvi Satalkar, Shashank Narayan Kane, Tetiana Tatarchuk, and João Pedro Araújo 24 Dielectric Properties and AC Conductivity of Epoxy/Hybrid Nanocarbon Filler Composites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377 Ludmila L. Vovchenko, Ludmila Yu. Matzui, Yulia S. Perets, and Yurii S. Milovanov 25 Obtaining of the Modified NH4 NO3 Granules with 3-D Nanoporous Structure: Impact of Humidifier Type on the Granule’s Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 395 A. E. Artyukhov, J. Gabrusenoks, and P. C. Rossi 26 Bifunctional Silicas with Immobilized Lignin . . . . . . . . . . . . . . . . . . . . . . . . . . . 407 Yulia Bolbukh, Stanislav Sevostianov, Beata Podkoscielna, Dariusz Sternik, Panagiotis Klonos, Polycarpos Pissis, Barbara Gawdzik, and Valentin Tertykh x Contents 27 Cooperative Phenomena in Spin-Crossover Molecular Crystals . . . . . . 427 Iurii Gudyma, Artur Maksymov, and Kateryna Polonska 28 Copper Nucleation on Nickel from Pyrophosphate-Based Polyligand Electrolyte . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 443 Antonnia Maizelis and Boris Bairachniy 29 Structural Study of the Modified Cu0.4 Co0.4 Ni0.4 Mn1.8 O4 and Cu0.1 Ni0.8 Co0.2 Mn1.9 O4 Ceramics Using Combined Methods . . . 459 H. Klym, I. Hadzaman, A. Ingram, O. Shpotyuk, I. Karbovnyk, Yu. Kostiv, I. Vasylchyshyn, and D. Chalyy 30 Effect of a Hydrogen Sulfide-Containing Atmosphere on the Physical and Mechanical Properties of Solid Oxide Fuel Cell Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 475 B. D. Vasyliv, V. Ya. Podhurska, O. P. Ostash, and V. V. Vira 31 Influence of Annealing in Vacuum on Dispersion Kinetics of Titanium and Zirconium Nanofilms Deposited onto Oxide Materials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 487 Y. V. Naidich, I. I. Gab, T. V. Stetsyuk, B. D. Kostyuk, O. M. Fesenko, and D. B. Shakhnin 32 Grain Porous Structure and Exploitation Properties of Humidity-Sensitive Magnesium Aluminate Spinel-Type Ceramics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 499 H. Klym, I. Hadzaman, O. Shpotyuk, and A. Ingram Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 521 Contributors M. V. Abramov Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Viktor Antsibor University “Ukraine”, Kyiv, Ukraine Dumlupinar University, Kutahya, Turkey João Pedro Araújo IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Department of Physics and Astronomy, Faculty of Sciences, University of Porto, Porto, Portugal A. E. Artyukhov Processes and Equipment of Chemical and Petroleum Refinery Department, Sumy State University, Sumy, Ukraine Ihor Astrelin Department of Chemistry, National Technical University of Ukraine, “KPI”, Kyiv, Ukraine Boris Bairachniy National Technical University “Kharkiv Polytechnic Institute”, Kharkiv, Ukraine V. A. Bershtein Ioffe Institute, St. Petersburg, Russia Gisele Boiteux Université de Lyon, Université Lyon 1, Ingénierie des Matériaux Polymères, UMR CNRS 5223, Villeurbanne, France Yulia Bolbukh Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine T. M. Budnyak Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine A. Burlaka R.E. Kavetsky Institute of Experimental Pathology, Oncology and Radiobiology of the National Academy of Sciences of Ukraine, Kyiv, Ukraine D. Chalyy Lviv State University of Life Safety, Lviv, Ukraine xi xii Contributors V. Demchenko Institute of Macromolecular Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine Zbigniew Dendzik Institute of Physics, University of Silesia, Chorzow, Poland Silesian Center for Education and Interdisciplinary Research, University of Silesia, Chorzow, Poland O. A. Diyuk Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Kyiv, Ukraine Tetiana Dontsova Department of Inorganic Substances Technology, Water Treatment and General Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine Yuliya Dzyazko V. I. Vernadsky Institute of General and Inorganic Chemistry of the National Academy of Science of Ukraine, Kyiv, Ukraine Yurii Fedenko Department of Inorganic Substances Technology, Water Treatment and General Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine O. M. Fesenko Institute of Physics of National Academy Sciences of Ukraine, Kyiv, Ukraine L. A. Frolova Ukrainian State Chemical Technology University, Dnipro, Ukraine Angelina Gab University “Ukraine”, Kyiv, Ukraine I. I. Gab Frantsevich Institute for Problems of Materials Science of National Academy Sciences of Ukraine, Kyiv, Ukraine J. Gabrusenoks Institute of Solid State Physics, University of Latvia, Riga, Latvia Marcelle Gaune-Escard Ecole Polytechnique, CNRS UMR 6595, Technopôle deChateau Gombert, Marseille Cedex 13, France Barbara Gawdzik Faculty of Chemistry, Maria Curie-Sklodowska University, Lublin, Poland Zygmunt Gburski Institute of Physics, University of Silesia, Katowice, Poland Silesian Centre of Education & Interdisciplinary Research, Chorzów, Poland L. Goncharenko Institute of Macromolecular Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine P. P. Gorbyk Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Krzysztof Górny Institute of Physics, University of Silesia, Chorzow, Poland Silesian Center for Education and Interdisciplinary Research, University of Silesia, Chorzow, Poland Contributors xiii Iurii Gudyma Department of General Physics, Technical and Computer Sciences, Yuriy Fedkovych Chernivtsi National University, Chernivtsi, Ukraine I. Hadzaman Drohobych State Pedagogical University, Drohobych, Ukraine V. O. Hryn Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine A. Ingram Opole University of Technology, Opole, Poland Oleksandr Ishtvanik University “Ukraine”, Kyiv, Ukraine Maksym V. Iurzhenko Institute of Macromolecular Chemistry of National Academy of Sciences, Kyiv, Ukraine Iryna Ivanenko Department of Inorganic Substances Technology, Water Treatment and General Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine Shashank Narayan Kane Magnetic Materials Laboratory, School of Physics, D. A. University, Indore, India L. V. Karabanova Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine I. Karbovnyk Ivan Franko National University of Lviv, Lviv, Ukraine Panagiotis Klonos Department of Physics, National Technical University of Athens, Athens, Greece H. Klym Lviv Polytechnic National University, Lviv, Ukraine S. Kobylinskyi Institute of Macromolecular Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine S. V. Kolotilov L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine Yu. Kostiv Lviv Polytechnic National University, Lviv, Ukraine B. D. Kostyuk Frantsevich Institute for Problems of Materials Science of National Academy Sciences of Ukraine, Kyiv, Ukraine I. G. Kovzun F. D. Ovcharenko Institute of Biocolloid Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Roman Kozakevych Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine O. A. Kushnerov Oles Honchar Dnipropetrovsk National University, Dnipro, Ukraine N. V. Kusyak Ivan Franko Zhytomyr State University, Zhytomyr, Ukraine N. Kutsevol National Taras Shevchenko University of Kyiv, Kyiv, Ukraine xiv Contributors A. W. Lloyd University of Brighton, Brighton, UK Tetiana Lukashenko University “Ukraine”, Kyiv, Ukraine S. Lukin R.E. Kavetsky Institute of Experimental Pathology, Oncology and Radiobiology of the National Academy of Sciences of Ukraine, Kyiv, Ukraine Lucian Lupascu Institute of Chemistry of the Academy of Sciences of Moldova, Chisinau, Republic of Moldova Tudor Lupascu Institute of Chemistry of the Academy of Sciences of Moldova, Chisinau, Republic of Moldova Antonnia Maizelis National Technical University ”Kharkiv Polytechnic Institute”, Kharkiv, Ukraine D. Makieła Institute of Physics, University of Silesia, Katowice, Poland Silesian Centre of Education & Interdisciplinary Research, Chorzów, Poland Artur Maksymov Marian Smoluchowski Institute of Physics, Jagiellonian University, Krakow, Poland Viktor Malyshev University “Ukraine”, Kyiv, Ukraine Yevgen P. Mamunya Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Liubov K. Matkovska Institute of Macromolecular Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Université de Lyon, Université Lyon 1, Ingénierie des Matériaux Polymères, UMR CNRS 5223, Villeurbanne, France Ludmila Yu. Matzui Departments of Physics and Institute of High Technologies, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine S. V. Mikhalovsky University of Brighton, Brighton, UK Yurii S. Milovanov Departments of Physics and Institute of High Technologies, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine O. Nadtoka National Taras Shevchenko University of Kyiv, Kyiv, Ukraine Svitlana Nahirniak Faculty of Chemical Technology, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine Y. V. Naidich Frantsevich Institute for Problems of Materials Science of National Academy Sciences of Ukraine, Kyiv, Ukraine S. G. Nedilko Taras Shevchenko National University of Kyiv, Kyiv, Ukraine V. Neimash Institute of Physics of the National Academy of Sciences of Ukraine, Kyiv, Ukraine Contributors xv Tatyana A. Nenastina National Technical University “Kharkiv Polytechnic Institute”, Kharkiv, Ukraine O. M. Nikipelova State agency “Ukrainian Research Institute of Medical Rehabilitation and Balneology, Ministry of Health of Ukraine”, Odessa, Ukraine V. O. Oliinyk F. D. Ovcharenko Institute of Biocolloid Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine A. Onanko National Taras Shevchenko University of Kyiv, Kyiv, Ukraine V. Orel National Cancer Institute, Kyiv, Ukraine National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine O. P. Ostash Karpenko Physico-Mechanical Institute of the National Academy of Sciences of Ukraine, Lviv, Ukraine Mateusz Pabiszczak Institute of Physics, University of Silesia, Katowice, Poland Silesian Centre of Education & Interdisciplinary Research, Chorzów, Poland A. V. Panko F. D. Ovcharenko Institute of Biocolloid Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Yulia S. Perets Departments of Physics and Institute of High Technologies, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine V. Ya. Podhurska Karpenko Physico-Mechanical Institute of the National Academy of Sciences of Ukraine, Lviv, Ukraine A. L. Petranovska Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Polycarpos Pissis Department of Physics, National Technical University of Athens, Athens, Greece O. A. Pivovarov Ukrainian State Chemical Technology University, Dnipro, Ukraine Beata Podkoscielna Faculty of Chemistry, Maria Curie-Sklodowska University, Lublin, Poland Kateryna Polonska Department of General Physics, Institute of Physical, Technical and Computer Sciences, Yuriy Fedkovych Chernivtsi National University, Chernivtsi, Ukraine Ludmila Ponomarova V. I. Vernadsky Institute of General and Inorganic Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine V. A. Prokopenko F. D. Ovcharenko Institute of Biocolloid Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine National Technical University of Ukraine “KPI”, Kyiv, Ukraine xvi Contributors Ie. V. Pylypchuk Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Violetta Raczyńska Institute of Physics, University of Silesia, Chorzow, Poland Przemysław Raczyński Institute of Physics, University of Silesia, Chorzow, Poland Silesian Center for Education and Interdisciplinary Research, University of Silesia, Chorzow, Poland S. Riabov Institute of Macromolecular Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine A. Romanov National Cancer Institute, Kyiv, Ukraine P. C. Rossi Department of Chemical Technology, National University of Río Cuarto, Río Cuarto, Córdoba, Argentina V. I. Rudenko Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine N. Rybalchenko Zabolotny Institute of Microbiology and Virology, The National Academy of Sciences of Ukraine, Kyiv, Ukraine O. Rykhalskyi National Cancer Institute, Kyiv, Ukraine National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine O. V. Sachuk Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Kyiv, Ukraine Nikolay D. Sakhnenko National Technical University “Kharkiv Polytechnic Institute”, Kharkiv, Ukraine Manvi Satalkar Magnetic Materials Laboratory, School of Physics, D. A. University, Indore, India Z. Sawlowicz Institute of Geology, Jagiellonian University, Krakow, Poland Sergey Scherbakov M. G. Kholodny Institute of Botany of the National Academy of Science of Ukraine, Kyiv, Ukraine Stanislav Sevostianov Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine D. B. Shakhnin V.I. Vernadsky Institute of General and Inorganic Chemistry of National Academy Sciences of Ukraine, Kyiv, Ukraine Dmytro Shakhnin University “Ukraine”, Kyiv, Ukraine S. M. Shcherbakov M. G. Kholodny Institute of Botany of the National Academy of Science of Ukraine, Kyiv, Ukraine Contributors xvii A. Shevchenko G.V. Kurdyumov Institute for Metal Physics of the National Academy of Sciences of Ukraine, Kyiv, Ukraine O. Shpotyuk Vlokh Institute of Physical Optics, Lviv, Ukraine Jan Dlugosz University in Czestochowa, Czestochowa, Poland T. N. Smirnova Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine Valentin Sosenkin A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Science, Moscow, Russia V. L. Starchevskyy National University “Lviv Polytechnic”, Lviv, Ukraine Dariusz Sternik Faculty of Chemistry, Maria Curie-Sklodowska University, Lublin, Poland Andrew Stetsko Faculty of computer engineering printing, Ukraine Academy of Printing, Lviv, Ukraine T. V. Stetsyuk Frantsevich Institute for Problems of Materials Science of National Academy Sciences of Ukraine, Kyiv, Ukraine Tetiana Tatarchuk Department of Pure and Applied Chemistry, Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine Educational and Scientific Center of Chemical Materials Science and Nanotechnology, Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, Ukraine Valentin Tertykh Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kyiv, Ukraine N. M. Tolstopalova National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine O. A. Tsyganovich F. D. Ovcharenko Institute of Biocolloid Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine S. P. Turanksa Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, Kyiv, Ukraine Nataliia Uskova University “Ukraine”, Kyiv, Ukraine Dumlupinar University, Kutahya, Turkey Zafer Ustundag University “Ukraine”, Kyiv, Ukraine Dumlupinar University, Kutahya, Turkey I. Vasylchyshyn Lviv Polytechnic National University, Lviv, Ukraine B. D. Vasyliv Karpenko Physico-Mechanical Institute of the National Academy of Sciences of Ukraine, Lviv, Ukraine xviii Contributors Maryna V. Ved National Technical University “Kharkiv Polytechnic Institute”, Kharkiv, Ukraine V. V. Vira Lviv Polytechnic National University, Lviv, Ukraine Yurii Volfkovich A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Science, Moscow, Russia Ludmila L. Vovchenko Departments of Physics and Institute of High Technologies, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine R. L. Whitby University of Brighton, Brighton, UK P. N. Yakushev Ioffe Institute, St. Petersburg, Russia Iryna Yu. Yermolenko National Technical University “Kharkiv Polytechnic Institute”, Kharkiv, Ukraine O. I. Zakutevskyy Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Kyiv, Ukraine V. A. Zazhigalov Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Kyiv, Ukraine Part I Nanochemistry and Biotechnology